It's all about English alphabet
My first is double twenty-one but twice of twenty-two, 21=u*2=W; 22=v*2=W
Decipher it and you will see that statement is quite true.
My next two are just three apart, or, looking at the link, Link=OR
You'll have the answer easily and will not have to think.
My fourth is so more ways than one, so long as you can spell, =D
While my fifth splits first and second, so what is it? Can you tell? = S between W & O
It may seem like these words of rhyme are nonsense things to say,
Though the five together are right here (two ways) so what are they?